3 years ago

Synthesis and Molecular Structure of a Novel Compound Containing a Carbonate-Bridged Hexacalcium Cluster Cation Assembled on a Trimeric Trititanium(IV)-Substituted Wells–Dawson Polyoxometalate

Synthesis and Molecular Structure of a Novel Compound Containing a Carbonate-Bridged Hexacalcium Cluster Cation Assembled on a Trimeric Trititanium(IV)-Substituted Wells–Dawson Polyoxometalate
Yusuke Matsuki, Takuya Kaneko, Takahiro Hoshino, Rina Isobe, Kenji Nomiya
A novel hexacalcium cluster cation containing a carbonate ligand and one calcium cation assembled on a trimeric trititanium(IV)-substituted Wells−Dawson polyoxometalate, [{Ca6(CO3)(μ3-OH)(OH2)18}(P2W15Ti3O61)3Ca(OH2)3]19- (Ca7Ti9Trimer), was obtained by the reaction of calcium chloride and in situ generated monomeric “[P2W15Ti3O59(OH)3]9−” (Ti3Monomer) under basic conditions; the molecular and crystal structures were determined.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01043

DOI: 10.1021/acs.inorgchem.7b01043

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