5 years ago

Probing Interligand Electron Transfer in the 1MLCT S1 Excited State of trans-Mo2L2L′2 Compounds: A Comparative Study of Auxiliary Ligands and Solvents

Probing Interligand Electron Transfer in the 1MLCT S1 Excited State of trans-Mo2L2L′2 Compounds: A Comparative Study of Auxiliary Ligands and Solvents
Judith C. Gallucci, Ewan J. M. Hamilton, Changcheng Jiang, Samantha E. Brown-Xu, Philip J. Young, Malcolm H. Chisholm, William T. Kender
The interligand charge dynamics in the 1MLCT S1 states of dimolybdenum paddlewheel compounds were studied with femtosecond time-resolved infrared (fs-TRIR) spectroscopy. The influence of interligand electronic coupling in the excited states was displayed by tuning the electronic properties of the dimetal center with carboxylate ligands. Solute−solvent interactions show limited influence despite the expected large dipole moments of the 1MLCT S1 states.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01164

DOI: 10.1021/acs.inorgchem.7b01164

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