3 years ago

Regioselective Ene-Type Allylic Chlorination of Electron-Rich Alkenes by Activated DMSO

Regioselective Ene-Type Allylic Chlorination of Electron-Rich Alkenes by Activated DMSO
Alexandros L. Zografos, Stavroula Pappa, Vera P. Demertzidou, Vasiliki Sarli
A simple protocol involving the activation of DMSO by chlorotrimethysilane is described for the chemoselective chlorination of polyprenoids. The proposed protocol provides a versatile and scalable alternative to existing routes for accessing useful synthetic synthons for the synthesis of complex terpenoids.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b01103

DOI: 10.1021/acs.joc.7b01103

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