Inorganic Chemistry
Inorganic Chemistry
5 years ago

Ytterbium and Europium Complexes of Redox-Active Ligands: Searching for Redox Isomerism

Ytterbium and Europium Complexes of Redox-Active Ligands: Searching for Redox Isomerism
Victor I. Ovcharenko, Igor L. Fedushkin, Ekaterina M. Zueva, Serhiy Demeshko, Artem S. Bogomyakov, Evgeny V. Baranov, Alexandra A. Skatova, Dmitriy S. Yambulatov
The reactions of the isostructural complexes of EuII and YbII (dpp-Bian)Ln(dme)2 (Ln = Eu, 3; Yb, 4) with 2,2′- bipyridine afford virtually redox-isomeric complexes 9 and 10. Despite the same coordination environment the molecules of 9 and 10 differ in the charge distribution between the metal and bipy ligand.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01344

DOI: 10.1021/acs.inorgchem.7b01344

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