3 years ago

MAu2GeS4-Chalcogel (M = Co, Ni): Heterogeneous Intra- and Intermolecular Hydroamination Catalysts

MAu2GeS4-Chalcogel (M = Co, Ni): Heterogeneous Intra- and Intermolecular Hydroamination Catalysts
Alexander Rothenberger, Abdul-Hamid Emwas, Bambar Davaasuren
The first chalcogenide based aerogel (chalcogel) heterogeneous hydroamination catalysts, MAu2GeS4-chalcogel (M = Co, Ni), were successfully synthesized and characterized. MAu2GeS4-chalcogels possess high surface area and macroporosity and contain M2+ catalytic active centers confined inside the 3D covalent network. The catalysts were active for both intra- and intermolecular hydroamination reactions and demonstrated excellent recoverability after multiple catalytic cycles and regioselectivity toward the Markovnikov products.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01099

DOI: 10.1021/acs.inorgchem.7b01099

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.