Journal of the American Chemical Society
Journal of the American Chemical Society
4 years ago

Cascade Polymerization via Controlled Tandem Olefin Metathesis/Metallotropic 1,3-Shift Reactions for the Synthesis of Fully Conjugated Polyenynes

Cascade Polymerization via Controlled Tandem Olefin Metathesis/Metallotropic 1,3-Shift Reactions for the Synthesis of Fully Conjugated Polyenynes
Hyeon Park, Tae-Lim Choi, Jin-Kyung Lee, Cheol Kang
We demonstrate the first example of cascade polymerization by combining olefin metathesis and metallotropic 1,3-shift reactions to form unique conjugated polyenynes. Rational design of monomers enabled controlled polymerization, and kinetic investigation of the polymerization mechanism was conducted.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b04913

DOI: 10.1021/jacs.7b04913

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