3 years ago

CuH-catalysed hydroamination of arylalkynes with hydroxylamine esters - a computational scrutiny of rival mechanistic pathways

CuH-catalysed hydroamination of arylalkynes with hydroxylamine esters - a computational scrutiny of rival mechanistic pathways
Sven Tobisch
An in-depth computational mechanistic probe of the CuH-mediated hydroamination of internal arylalkynes with amine electrophile and hydrosilane defines the most accessible pathways for rival avenues of direct and reductive hydroamination, from which a general understanding of the factors controlling formal hydroamination catalysis emerges.

Publisher URL: http://feeds.rsc.org/~r/rss/SC/~3/SAJFi-MfOgE/C7SC01107E

DOI: 2017/SC/C7SC01107E

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