5 years ago

Palladium-catalyzed regio- and chemoselective direct desulfitative arylation of anilides with arylsulfonyl chlorides

Palladium-catalyzed regio- and chemoselective direct desulfitative arylation of anilides with arylsulfonyl chlorides
A straightforward and practical palladium-catalyzed regioselective arylation of anilides is described. This method provides a new approach to prepare 2-aminobiaryls, which are valuable precursors for the synthesis of various N-containing heterocycles, using arylsulfonyl chlorides as readily available arylating agents.

Publisher URL: www.sciencedirect.com/science

DOI: S0040402017307469

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