Chemistry - A European Journal
Chemistry - A European Journal
5 years ago

Ligand- and Solvent-Tuned Chemoselective Carbonylation of Bromoaryl Triflates

Ligand- and Solvent-Tuned Chemoselective Carbonylation of Bromoaryl Triflates
Chaoren Shen, Xiao-Feng Wu, Haijun Jiao, Zhihong Wei
A palladium-catalyzed chemoselective carbonylative transformation of bromoaryl triflates has been established. The selective C−Br versus C−OTf functionalization can be remarkably tuned by the combination of ligand (Xantphos vs. DPPF) and solvent (toluene vs. DMSO). The respective ligand and solvent effects were rationalized by DFT calculations. More information can be found in the Full Paper by H. Jiao and X. F. Wu et al. (DOI: 10.1002/chem.201702015).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201703190

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.