Oxidative addition/cycloaddition of arenesulfonamides and triflamide to N-allyltriflamide and N,N-diallyltriflamide

5 years ago

Oxidative addition/cycloaddition of arenesulfonamides and triflamide to N-allyltriflamide and N,N-diallyltriflamide

B. A. Shainyan, M. Yu Moskalik, A. S. Ganin, V.[space]V. Astakhova, I. V. Sterkhova

Mono- and diallyltriflamides react with triflamide in the oxidative system t-BuOCl + NaI to give the products of addition and cycloaddition, unlike the reaction of N-allyltriflamide with arenesulfonamides or trifluoroacetamide leading to chlorination and cyclodimerization.

Publisher URL: http://feeds.rsc.org/~r/rss/ra/~3/KYgG7j6BqXc/C7RA05831D

DOI: 2017/RA/C7RA05831D

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