3 years ago

Synthesis and Reactivity of Fluoroalkyl Copper Complexes by the Oxycupration of Tetrafluoroethylene

Synthesis and Reactivity of Fluoroalkyl Copper Complexes by the Oxycupration of Tetrafluoroethylene
Takuya Adachi, Sensuke Ogoshi, Naoyoshi Ishida, Masato Ohashi, Kotaro Kikushima
The copper(I)-mediated generation of -OCF2CF2- moieties by the oxycupration of tetrafluoroethylene using either copper aryloxides or alkoxides is described by S. Ogoshi et al. (DOI: 10.1002/anie.201703923). The key intermediates, 2-aryloxy- and 2-alkyloxy-1,1,2,2-tetrafluoroethyl copper complexes were obtained and subsequently reacted with aryl iodides to afford ROCF2CF2Ar (R=aryl or alkyl) in high yields.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201707624

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