3 years ago

Back Contact Engineering for Increased Performance in Kesterite Solar Cells

Back Contact Engineering for Increased Performance in Kesterite Solar Cells
Yun Seog Lee, Talia S. Gershon, Tayfun Gokmen, Saurabh Singh, Oki Gunawan, Douglas M. Bishop, Priscilla D. Antunez, Richard Haight, Teodor K. Todorov
The thin-film photovoltaic absorber Cu2ZnSn(S,Se)4 (CZTSSe) holds considerable promise for large scale conversion of sunlight into electricity. CZTSSe is composed of Earth-abundant elements that exhibit low-toxicities, but improvements in device efficiency have been hampered by difficulties in increasing open circuit voltages (VOC) due, at least in part, to disorder induced band tailing. We present a method to increase VOC through direct modification of the back contact; our approach involves the separation of fully functioning devices from their Mo/glass substrate to reveal the back CZTSSe surface. Formation of a new back contact consisting of a thermally deposited high work function material (MoO3), together with a higly reflective (Au) capping layer, creates an electrostatic field that drives electrons to the front p-n junction and leads to a decrease in electron-hole recombination. Model simulations indicating an increase in VOC with decreasing absorber thickness are borne out by experiments with devices of varying thicknesses (0.7–2.0 μm). We report VOC increases of up to 49 mV for a 1 μm thick absorber, with even greater increases up to 61 mV when the back CZTSSe surface is etched with bromine-methanol. High performing kesterite photovoltaic devices show improved efficiency parameters after exfoliation and back contact engineering. The use of a high work function material (MoO3) and a reflective back contact (Au) results in higher open circuit voltage (VOC) and short circuit current (JSC), which closely match model simulations.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/aenm.201602585

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.