Inorganic Chemistry
Inorganic Chemistry
4 years ago

Transformation of Structure, Electrical Conductivity, and Magnetism in AA′Fe2O6−δ, A = Sr, Ca and A′ = Sr

Transformation of Structure, Electrical Conductivity, and Magnetism in AA′Fe2O6−δ, A = Sr, Ca and A′ = Sr
Suresh Mulmi, Farshid Ramezanipour, Ashfia Huq, Ram Krishna Hona
The transformation of structural ordering scheme, magnetic structure, and charge transport properties has been studied in AA′Fe2O6−δ, where A = Sr, Ca and A′ = Sr. The magnetic structure is transformed from a system with moments in spin-density wave state into one with G-type antiferromagnetic order upon changing the A-site cation. In addition, the metallic behavior of the Sr2 compound is converted into semiconductivity in the CaSr material, which also shows mixed ionic−electronic conductivity.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01228

DOI: 10.1021/acs.inorgchem.7b01228

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