Crystal Growth & Design
Crystal Growth & Design
4 years ago

Magnetic Lotus Root Based on a Cyanido-Bridged Co–W Metal Assembly

Magnetic Lotus Root Based on a Cyanido-Bridged Co–W Metal Assembly
Shin-ichi Ohkoshi, Szymon Chorazy, Barbara Sieklucka, Yasuto Miyamoto, Daisuke Takahashi, Koji Nakabayashi, Masaya Komine
A three-dimensional cyanido-bridged Co−W metal assembly of Co7[W(CN)8]4Cl2·29H2O was synthesized. The crystal structure has large channels with a maximum diameter of ca. 1.4 nm, occupied by noncoordinated water molecules. The compound exhibits apparent long-range magnetic ordering with Curie temperature of 29 K and coercive field of 5500 Oe.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00794

DOI: 10.1021/acs.cgd.7b00794

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