Inorganic Chemistry
Inorganic Chemistry
5 years ago

The Inductive Effect of Neighboring Cations in Tuning Luminescence Properties of the Solid Solution Phosphors

The Inductive Effect of Neighboring Cations in Tuning Luminescence Properties of the Solid Solution Phosphors
Zhendong Hao, Wenge Xiao, Xia Zhang, Dan Wu, Xuewei Ba, Ligong Zhang, Liangliang Zhang, Guo-Hui Pan, Jiahua Zhang
The color tunable solid solution phosphors based on Eu2+ activated K2Al2B2O7 indicate that the variations of centroid shift and Stokes shift can play key roles in regulating the luminescence properties. A general model involving the inductive effect of neighboring cations is proposed to explain the so-called abnormal emission shift, thus offering some guidelines for designing solid solution phosphors.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01457

DOI: 10.1021/acs.inorgchem.7b01457

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