3 years ago

Ligand Configuration-Induced Manganese(II) Coordination Polymers: Syntheses, Crystal Structures, Sorption, and Magnetic Properties

Ligand Configuration-Induced Manganese(II) Coordination Polymers: Syntheses, Crystal Structures, Sorption, and Magnetic Properties
Yao-Yu Wang, Kun Zhang, Hong-Yun Yang, Wen-Juan Shi, Lei Hou, Li-Yun Du
Through tuning reaction conditions, the assembly of Mn2+ ions and a pyrazinyl-bitriazole ligand with different geometric configurations afforded three CPs, which show diverse cluster-based frameworks, and revealed different magnetic properties as well as the rare gate-opening phenomenon for CO2 gas adsorption.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01657

DOI: 10.1021/acs.inorgchem.7b01657

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