Crystal Growth & Design
Crystal Growth & Design
5 years ago

Interconversion of One-Dimensional Thiogallates Cs2[Ga2(S2)2–xS2+x] (x = 0, 1, 2) by Using High-Temperature Decomposition and Polysulfide-Flux Reactions

Interconversion of One-Dimensional Thiogallates Cs2[Ga2(S2)2–xS2+x] (x = 0, 1, 2) by Using High-Temperature Decomposition and Polysulfide-Flux Reactions
Daniel Friedrich, Marc Schlosser, Arno Pfitzner
One-dimensional thiogallates CsGaS2-mC16, Cs2Ga2S5, and CsGaS3 not only feature similar polymeric anions but also can actually be interconverted using different methods. At high temperatures, a degradation of the disulfide units in these chains takes place. This irreversible process can only be reversed by using a polysulfide-flux synthesis route.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00840

DOI: 10.1021/acs.cgd.7b00840

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