Inorganic Chemistry
Inorganic Chemistry
5 years ago

Synthesis of a Series of Heavy Lanthanide(III) Monoporphyrinato Complexes with Tetragonal Symmetry

Synthesis of a Series of Heavy Lanthanide(III) Monoporphyrinato Complexes with Tetragonal Symmetry
Akira Fuyuhiro, Naoto Ishikawa, Takamitsu Fukuda, Anas Santria
The crystal structures of lanthanide(III) monoporphyrinato complexes are rarely reported. Here, a series of the complexes, formulated in [Ln(TPP)(cyclen)]Cl and having a strict four-fold symmetry axis, were successfully obtained in mild conditions and crystallized in a tetragonal system with very similar lattice parameters. By varying lanthanide ions, the average Ln−N and interplanar distances (dN) decrease with decreasing lanthanide(III) ionic radii and give a monotonic shift to the absorption spectra.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01546

DOI: 10.1021/acs.inorgchem.7b01546

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.