Sulfoximidoyl-Containing Hypervalent Iodine(III) Reagents: 1-Sulfoximidoyl-1,2-benziodoxoles

5 years ago

Sulfoximidoyl-Containing Hypervalent Iodine(III) Reagents: 1-Sulfoximidoyl-1,2-benziodoxoles

Han Wang, He Sheng, Duo Zhang, Carsten Bolm

Treatment of NH-sulfoximines with pseudocyclic benziodoxole triflate results in N–I bond formation leading to a new type of sulfoximidoyl-containing hypervalent iodine(III) reagents in high yields. Degradation studies revealed a pronounced stability in both the solid state and in solution.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b01535

DOI: 10.1021/acs.joc.7b01535

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