3 years ago

Histaminol and its complexes with copper(II) - studies in solid state and solution

Maciej Witwicki, Anna Dołęga, Piotr Maślewski, Dariusz Wyrzykowski
Histaminol (4(5) (β-hydroxyethyl)imidazole, 4-(1H-Imidazol-2-yl)ethanol, L) is an analogue of histamine and its minor metabolite. So far its properties have not been studied in detail due to the synthetic difficulties. Here the structure and acid-base properties of histaminol as well as the results of studies on its copper(II) complexes in solid state and aqueous solution are reported. Stability constants of the histaminol - Cu(II) system are measured and each stage of the complex formation is illustrated with the relevant crystal structure and the EPR spectrum.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/ejic.201701411

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