3 years ago

A Borane Platinum Complex Undergoing Reversible Hydride Migration in Solution

A Borane Platinum Complex Undergoing Reversible Hydride
Migration in Solution
Abdollah Neshat, Behrouz Notash, Stefano Todisco, Mohsen Golbon Haghighi, Piero Mastrorilli, Hamid R. Shahsavari
The complex {[(κ3-S,B,S-HB(mb)2]Pt(κ2-C,N-ppy)H}, 2, features a strong reverse-dative Pt → B σ interaction in the solid state and undergoes a reversible Pt−H bond activation in solution, establishing an equilibrium between the hexacoordinated 2 and the tetracoordinate complex {[(κ2-S,S-H2B(mb)2]Pt(κ2-C,N-ppy)}, 3. Hydrolysis of the B−N bond in 2 affords a dimeric half-lantern platinum(II,II) complex [{Pt(κ2-C,N-ppy)(μ22-N,S-mb)}2], 4.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b02807

DOI: 10.1021/acs.inorgchem.7b02807

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