3 years ago

Facile Silylation of Cyclitols Using Silyl Bis(triflates)

Martin Köckerling, Anke Topp, Constantin Mamat, Ralf Miethchen, Helmut Reinke
Novel silylated diols and polyols were prepared using a recently developed synthesis route with bifunctionalized silyl triflates. These silyl derivatives include two triflate functions which allow a selective protection of two hydroxyl groups. Moreover, the conformation of the silyl chain in the silane backbone led to exceptional UV properties.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/ejic.201701327

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