5 years ago

Synthesis and Characterization of an Isomorphous Lanthanide-Thiophenemonocarboxylate Series (Ln = La–Lu, except Pm) Amenable to Color Tuning

Synthesis and Characterization of an Isomorphous Lanthanide-Thiophenemonocarboxylate Series (Ln = La–Lu, except Pm) Amenable to Color Tuning
Jeffery A. Bertke, Paula M. Cantos, Rami J. Batrice, Karah E. Knope, Alyssa K. Adcock
An isomorphous series of lanthanide-thiophenemonocarboxylate compounds (Ln = La−Lu, except Pm) has been prepared under mild aqueous conditions. Efficient ligand-sensitized emission was observed in the visible region for Eu, Tb, and Dy, and in the NIR for Nd and Er. Mixed metal compounds containing Eu and Tb showed the ability to color tune emission from green through red.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00400

DOI: 10.1021/acs.cgd.7b00400

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