Crystal Growth & Design
Crystal Growth & Design
5 years ago

Co-Crystallization of Achiral Components into Chiral Network by Supramolecular Interactions: Coordination Complexes – Organic Radical

Co-Crystallization of Achiral Components into Chiral Network by Supramolecular Interactions: Coordination Complexes – Organic Radical
Kseniya Yu Maryunina, Katsuya Inoue, Sayaka Hatano, Sadafumi Nishihara, Yan-Li Gao, Mohamedally Kurmoo
Unexpected chiral co-crystals were generated from achiral organic radical and cis-MII(hfac)2(H2O)2 (M = Co or Mn). X-ray diffraction, infrared spectroscopy, and magnetization measurements collectively found the superposition of properties of the individual components without any charge or proton transfer confirming the genuine nature of co-crystals. The chirality is associated with the extensive supramolecular interactions in the solids.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00847

DOI: 10.1021/acs.cgd.7b00847

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