Inorganic Chemistry
Inorganic Chemistry
5 years ago

Synthesis of Denser Energetic Metal–Organic Frameworks via a Tandem Anion–Ligand Exchange Strategy

Synthesis of Denser Energetic Metal–Organic Frameworks via a Tandem Anion–Ligand Exchange Strategy
Michael Gozin, Yalu Dong, Shenghua Li, Pengcheng Zhang, Yao Du, Siping Pang, Hui Su, Jichuan Zhang
A tandem anion−ligand exchange strategy for synthesizing denser MOFs is proposed. By means of this strategy, we choose high-density nitroformate ion [C(NO2)3−] as an exogenous anion and water as an exogenous ligand to successfully synthesize two layered CMOFs. The resultant materials exhibit higher densities, higher heats of detonation, higher nitrogen and oxygen contents, and lower metal contents than their 3D precursors.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01122

DOI: 10.1021/acs.inorgchem.7b01122

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