Inorganic Chemistry
Inorganic Chemistry
5 years ago

Assembly of TeO32– Ions Embedded in an Nb/O Cage with Selective Decolorization of Organic Dye

Assembly of TeO32– Ions Embedded in an Nb/O Cage with Selective Decolorization of Organic Dye
Pengtao Ma, Junjun Sun, Jingping Wang, Jingyang Niu, Chao Zhang, Dongdi Zhang, Zhijie Liang
A novel tellurniobate species, [H2Te2Nb24O72]14−, was prepared that can be seen as a niobium cage containing two pyramidal {TeO3} groups. Alternatively, six Nb atoms are sandwiched between two {TeNb9}. This represents the largest telluroniobate aggreate and the first hexaniobate sandwich-type polyoxometalate. Furthermore, this compound exhibits activity for the decolorization of basic fuchsin.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b00860

DOI: 10.1021/acs.inorgchem.7b00860

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