Inorganic Chemistry
Inorganic Chemistry
5 years ago

Increase in the Magnetic Ordering Temperature (Tc) as a Function of the Applied Pressure for A2Mn[Mn(CN)6] (A = K, Rb, Cs) Prussian Blue Analogues

Increase in the Magnetic Ordering Temperature (Tc) as a Function of the Applied Pressure for A2Mn[Mn(CN)6] (A = K, Rb, Cs) Prussian Blue Analogues
C. M. Kareis, Y. Nakazawa, S. Yamashita, Joel S. Miller, J. G. DaSilva, H. Akutsu, M. Sugimoto
Pressure enhances the magnetic ordering temperature, Tc, for A2Mn[Mn(CN)6] (A = K, Rb, Cs) by 51, 46, and 24% at ∼1 GPa, respectively. The increase in Tc is attributed to deformation of the structure such that the MnII—N≡C angle decreases with increasing pressure, and the smaller the alkali cation, the greater the decrease in the MnII—N≡C angle.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01402

DOI: 10.1021/acs.inorgchem.7b01402

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