Inorganic Chemistry
Inorganic Chemistry
5 years ago

Structure-Directing Role of Phosphonate in the Synthesis of High-Nuclearity Silver(I) Sulfide-Ethynide-Thiolate Clusters

Structure-Directing Role of Phosphonate in the Synthesis of High-Nuclearity Silver(I) Sulfide-Ethynide-Thiolate Clusters
Thomas C. W. Mak, Guang-Xiong Duan, Han Cui, Xing Lu, Yun-Peng Xie, Jun-Ling Jin
Phosphonate ligands as structure-directing components have been employed to construct four new high-nuclearity silver(I) sulfide-ethynide-thiolate clusters, in which silver(I) aggregates tBuC≡C⊃Ag3, tBuC≡C⊃Ag4, and 2tBuC≡C⊃Ag7 are bridged by tBuS− ligands to engender respective silver(I) ethynide-thiolate clusters functioning as integral shell components, which are supported by phosphonate ligands. In each silver(I) sulfide-ethynide-thiolate cluster, a different encapsulated silver sulfide cluster serves as a core template.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01326

DOI: 10.1021/acs.inorgchem.7b01326

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