3 years ago

A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions

A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates
Exhibiting Coordination Number and Dimensional Reductions
Jian Lin, Mark A. Silver, Meiying Qie, Fang Kong, Jian-Qiang Wang, Hongliang Bao, Xiaomei Wang, Thomas E. Albrecht-Schmitt, Linjuan Zhang, Zenghui Yue
A large family of centrosymmetric and chiral f-element-bearing iodate selenates have been prepared hydrothermally and characterized. The lanthanide analogues exhibit coordination number and dimensional reductions as well as an increase in hydration across the entire 4f series due to the lanthanide contraction. Powder samples of LnISeO-3 exhibit moderate SHG responses (0.7 × KDP for the Gd analogue), suggesting that combining AO3 (C3v) and BO4 (Td) oxoanions can generate intriguing properties, such as SHG.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b03116

DOI: 10.1021/acs.inorgchem.7b03116

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