Chemistry - A European Journal
Chemistry - A European Journal
5 years ago

Alkoxides of Trivacant Lacunary Polyoxometalates

Alkoxides of Trivacant Lacunary Polyoxometalates
Kosuke Suzuki, Takuo Minato, Kazuya Yamaguchi, Noritaka Mizuno
Introduction of alkoxy protecting groups into the vacant sites of lacunary polyoxometalates (POMs) was demonstrated. By reacting organic-solvent-soluble trivacant lacunary Keggin-type POMs with methanol, six methoxy groups were introduced into the vacant sites. These monodentate alkoxy ligands could protect the reactive vacant sites and also easily be dissociated by hydrolysis. In contrast, the multidentate alkoxy ligands of pentaerythritol showed high resistance against hydrolysis, which allowed the synthesis of dimeric inorganic–organic–inorganic hybrid structures with the same or different heteroatoms. More information can be found in the Full Paper by K. Suzuki, N. Mizuno et al. (DOI: 10.1002/chem.201702883).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201703624

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.