Chemistry - A European Journal
Chemistry - A European Journal
5 years ago

Proton in a Confined Space: Structural Studies of H+⊂Crypt-111 Iodide and Some Halogen-Bonded Derivatives

Proton in a Confined Space: Structural Studies of H+⊂Crypt-111 Iodide and Some Halogen-Bonded Derivatives
Silvio Quici, Giuseppe Resnati, Michele R. Chierotti, Carlo Nervi, Roberto Gobetto, Vijith Kumar, Tullio Pilati
When a chemical entity is restrained in a cage most of its properties are redefined. Single-crystal X-ray analyses, solid-state 15N NMR techniques, and DFT calculations have been used to investigate the proton position and dynamics in H+⊂crypt-111 iodide and four halogen-bonded derivatives. The unique characteristics and distinctive features of the confined space within the cavity of crypt-111 are confirmed. More information can be found in the Full Paper by G. Resnati et al. (DOI: 10.1002/chem.201701699).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201703422

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