3 years ago

Gold(I)-Initiated Cycloisomerization/Diels–Alder/Retro-Diels–Alder Cascade Strategy to Biaryls

Gold(I)-Initiated Cycloisomerization/Diels–Alder/Retro-Diels–Alder Cascade Strategy to Biaryls
Yongxiang Liu, Shanshan Cui, Yangming Li, Lifeng Zhu, Bin Lin, Shengfei Jin, Zhiling Xiong, Maosheng Cheng, Chengjun Liu, Yujie Niu
A unique approach to biaryls was developed on the basis of propargyl vinyl ethers and dienophiles substrates via a gold(I)-initiated cycloisomerization/Diels–Alder/retro-Diels–Alder cascade reaction. The scope and mechanism of the reaction were investigated on the basis of a series of synthetic substrates, control experiments, and DFT calculations.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b01561

DOI: 10.1021/acs.joc.7b01561

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