Crystal Growth & Design
Crystal Growth & Design
5 years ago

Modulator Effect in UiO-66-NDC (1,4-Naphthalenedicarboxylic Acid) Synthesis and Comparison with UiO-67-NDC Isoreticular Metal–Organic Frameworks

Modulator Effect in UiO-66-NDC (1,4-Naphthalenedicarboxylic Acid) Synthesis and Comparison with UiO-67-NDC Isoreticular Metal–Organic Frameworks
Karl Petter Lillerud, Sachin M. Chavan, Sigurd Øien-Ødegaard, Unni Olsbye, Cesare Atzori, Aram L. Bugaev, Carlo Lamberti, Kirill A. Lomachenko, Vera V. Butova, Silvia Bordiga, Alexander V. Soldatov, Alexander A. Guda, Andriy P. Budnyk
The UiO-66-NDC metal−organic framework (MOF) (NDC = 1,4-naphthalenedicarboxylic) has been synthesized and characterized using different fractions of the benzene-carboxylic acid modulator vs NDC to tune structural properties of the final product. The modulator increases both the crystal size and the surface area of the product, but reduces its thermal stability owing to insertion of defects: missing linkers and missing Zr6(OH)4O4 clusters.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00892

DOI: 10.1021/acs.cgd.7b00892

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