Inorganic Chemistry
Inorganic Chemistry
5 years ago

Germanium and Tin Monoxides Trapped by Oxophilic Germylene and Stannylene Ligands

Germanium and Tin Monoxides Trapped by Oxophilic Germylene and Stannylene Ligands
Yuanyuan Su, Wenjun Zheng, Xiang Zhang, Herbert W. Roesky, Ying Yang, Yunxia Gao
Germanium and tin monoxides (GeO, SnO) were trapped by the respective 1,2,4-diazaphospholide-based germylene and stannylene M[3,5-tBu2dp]2 (M = Ge, Sn), resulting in the Lewis acid−base pair adducts M(μ-O)[M{η1(N)-(3,5-tBu2dp)}2]2.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b00918

DOI: 10.1021/acs.inorgchem.7b00918

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