5 years ago

In Situ Observation of Gas Adsorption onto ZIF-8 Using Terahertz Waves

In Situ Observation of Gas Adsorption onto ZIF-8 Using Terahertz Waves
Nobuaki Ogawa, Masafumi Odaka, Kyoko Umeno, Yutaro Watanabe, Takenori Tanno, Hirotoshi Matsumura, Atsushi Matsuoka
The adsorption behavior of energy-related gases onto ZIF-8 was investigated using terahertz waves. Comparison of the terahertz transmission spectra of ZIF-8 before and after exposure to the gases revealed that the 2 THz vibrational mode was involved in the gate-opening motion of organic linker molecules. The adsorption properties of each gas were detailed by monitoring the intensities of the 2 THz absorption peak.

Publisher URL: http://dx.doi.org/10.1021/acs.jpcc.7b04833

DOI: 10.1021/acs.jpcc.7b04833

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