3 years ago

Enabling high-rate electrochemical flow capacitors based on mesoporous carbon microspheres suspension electrodes

Enabling high-rate electrochemical flow capacitors based on mesoporous carbon microspheres suspension electrodes
Electrochemical flow capacitor (EFC) is a promising technology for grid energy storage, which combines the fast charging/discharging capability of supercapacitors with the scalable energy capacity of flow batteries. In this study, we report a high-power-density EFC using mesoporous carbon microspheres (MCMs) as suspension electrodes. By using a simple yet effective spray-drying technique, monodispersed MCMs with average particle size of 5 μm, high BET surface area of 1150–1267 m2 g−1, large pore volume of 2–4 cm3 g−1 and controllable mesopore size of 7–30 nm have been successfully prepared. The resultant MCMs suspension electrode shows excellent stability and considerable high capacitance of 100 F g−1 and good cycling ability (86% of initial capacitance after 10000 cycles). Specially, the suspension electrode exhibits excellent rate performance with 75% capacitance retention from 2 to 100 mV s−1, significantly higher than that of microporous carbon electrodes (20∼30%), due to the developed mesoporous channels facilitating for rapid ion diffusion. In addition, the electrochemical responses on both negative and positive suspension electrodes are studied, based on which an optimal capacitance matching between them is suggested for large-scale EFC unit.

Publisher URL: www.sciencedirect.com/science

DOI: S0378775317310261

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