3 years ago

Structural Diversities in Heterometallic Mn–Ca Cluster Chemistry from the Use of Salicylhydroxamic Acid: {MnIII4Ca2}, {MnII/III6Ca2}, {MnIII/IV8Ca}, and {MnIII8Ca2} Complexes with Relevance to Both High- and Low-Valent States of the Oxygen-Evolving Complex

Structural Diversities in Heterometallic Mn–Ca Cluster Chemistry from the Use of Salicylhydroxamic Acid: {MnIII4Ca2}, {MnII/III6Ca2}, {MnIII/IV8Ca}, and {MnIII8Ca2} Complexes with Relevance to Both High- and Low-Valent States of the Oxygen-Evolving Complex
Theocharis C. Stamatatos, Luís Cunha-Silva, Evangelia S. Koumousi, Catherine P. Raptopoulou, Vassilis Psycharis, Laura J. McCormick, Simon J. Teat, George Christou, Alysha A. Alaimo, Albert Escuer, Sayak Das Gupta, Chaoran Li, Shreya Mukherjee
The employment of salicylhydroxamic acid in heterometallic Mn−Ca chemistry has afforded four new cluster compounds with diverse structural topologies, metal stoichiometries, and oxidation-state descriptions.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01740

DOI: 10.1021/acs.inorgchem.7b01740

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