Inorganic Chemistry
Inorganic Chemistry
5 years ago

Electrical and Structural Characterization of Ba3Mo1–xNb1+xO8.5–x/2: The Relationship between Mixed Coordination, Polyhedral Distortion and the Ionic Conductivity of Ba3MoNbO8.5

Electrical and Structural Characterization of Ba3Mo1–xNb1+xO8.5–x/2: The Relationship between Mixed Coordination, Polyhedral Distortion and the Ionic Conductivity of Ba3MoNbO8.5
Abbie C. Mclaughlin, Sacha Fop, Eve J. Wildman, Clemens Ritter, Janet M. S. Skakle
Chemical doping studies, where Nb5+ substitutes Mo6+ in Ba3Mo1−xNb1+xO8.5−x/2, demonstrate that distortion of the d-metal polyhedra and the presence of (Mo/Nb)O4 tetrahedra with nonbridging apical oxygen atoms are important for the observation of significant ionic conduction in the Ba3MoNbO8.5 system.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01488

DOI: 10.1021/acs.inorgchem.7b01488

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