3 years ago

Tracking the Progress and Mechanism Study of a Solvothermal in Situ Domino N-Alkylation Reaction of Triethylamine and Ammonia Assisted by Ferrous Sulfate

Tracking the Progress and Mechanism Study of a Solvothermal in Situ Domino N-Alkylation Reaction of Triethylamine and Ammonia Assisted by Ferrous Sulfate
Tao Yang, Bin Liu, Ming-Hua Zeng, Jin-Ping Zhong, Bing-Feng Shi, Yue-Jin Liu, Mohamedally Kurmoo, Zhong-Hong Zhu
In situ triple N-alkylation of NEt3 by multidentate alcohol was assisted by FeSO4·7H2O,under solvothermal conditions, producing a trinuclear iron cluster. Real-time electrospray ionization mass spectrometry was used to detect key intermediates and to guide their isolation, which confirmed the domino nature of the reaction. A mechanism is proposed for the reaction.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01190

DOI: 10.1021/acs.inorgchem.7b01190

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