5 years ago

The Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)3]−—Synthesis and Reactivity

The Tris(pentafluoroethyl)stannate(II) Anion, [Sn(C2F5)3]−—Synthesis and Reactivity
Mark Niemann, Beate Neumann, Markus Wiesemann, Berthold Hoge, Johannes Klösener, Hans-Georg Stammler
The acidic tris(pentafluoroethyl)stannane sweetens the chemistry of tin. The reaction with the reversed polar tri-n-butyltin hydride afforded the highly polarized unsymmetrical distannane. In the reaction with bases, the three electron-withdrawing pentafluoroethyl substituents stabilize the readily transferable tris(pentafluoroethyl)stannate(II) anion, a compound which should not be missed in the cocktail of basic organotin chemistry. More information can be found in the Full Paper by B. Hoge et al. (DOI: 10.1002/chem.201702855).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201703335

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