5 years ago

Synthesis of Quinone Methide Substituted Neonicotinoid Derivatives via 1,6-Conjugate Addition of N-Benzyl Nitro Ketene Aminals with para-Quinone Methides Accompanying Oxidation

Synthesis of Quinone Methide Substituted Neonicotinoid Derivatives via 1,6-Conjugate Addition of N-Benzyl Nitro Ketene Aminals with para-Quinone Methides Accompanying Oxidation
Bao-Qu Wang, Qin Luo, Jun Lin, Sheng-Jiao Yan, Qiang Xiao
Neonicotinoid derivative synthesis via one-pot Cs2CO3-catalyzed 1,6-conjugate addition of NBNKAs and 1,1-enediamines with para-quinone methides in acetone and oxidation by oxygen has been developed.

Publisher URL: http://dx.doi.org/10.1021/acssuschemeng.7b02166

DOI: 10.1021/acssuschemeng.7b02166

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