4 years ago

Enantioselective Synthesis of Isoflavanones by Catalytic Dynamic Kinetic Resolution

Enantioselective Synthesis of Isoflavanones by Catalytic Dynamic Kinetic Resolution
Peter Metz, Tao Qin
A ruthenium-catalyzed asymmetric transfer hydrogenation of racemic isoflavanones with dynamic kinetic resolution yields virtually enantiopure isoflavanols as single diastereomers. Subsequent oxidation gives rise to isoflavanones in high enantiomeric purities.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b01218

DOI: 10.1021/acs.orglett.7b01218

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