5 years ago

Pincer-Supported Carbonyl Complexes of Cobalt(I)

Pincer-Supported Carbonyl Complexes of Cobalt(I)
Louise M. Guard, Donald E. Linn, Travis J. Hebden, D. Michael Heinekey
A pair of POCOP-supported mono- and dicarbonyl complexes of Co have been prepared and crystallographically characterized. The reactivity of (tBuPOCOP)Co(CO) with H2, acids, and carbon monoxide has been compared to that of the previously reported Rh and Ir counterparts. Co is found to share reactivity traits with both Rh and Ir.

Publisher URL: http://dx.doi.org/10.1021/acs.organomet.7b00434

DOI: 10.1021/acs.organomet.7b00434

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