5 years ago

Efficient Photoinduced Energy and Electron Transfer in ZnII-Porphyrin/Fullerene Dyads with Interchromophoric Distances up to 2.6 nm and No Wire-like Connectivity

Efficient Photoinduced Energy and Electron Transfer in ZnII-Porphyrin/Fullerene Dyads with Interchromophoric Distances up to 2.6 nm and No Wire-like Connectivity
Maida Vartanian, Nicola Armaroli, Uwe Hahn, Julien Iehl, Fernando Langa, Maria Vizuete, Jean-François Nierengarten, John Mohanraj, Béatrice Delavaux-Nicot, Andrea Barbieri
A series of rigid fullerene-porphyrin conjugates have been prepared. Whereas photoinduced energy transfer is still efficient whatever the distance, photoinduced electron transfer is virtually prevented at an interchromophoric distance above 2.5 nm even in polar benzonitrile. More information can be found in the Full Paper by N. Armaroli, F. Langa, B. Delavaux-Nicot, J.-F.  Nierengarten et al. (DOI: 10.1002/chem.201701668).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201703247

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