3 years ago

Low-Coordinate NHC-Cobalt(0)-Olefin Complexes: Synthesis, Structure, and Their Reactions with Hydrosilanes

Low-Coordinate NHC-Cobalt(0)-Olefin Complexes: Synthesis, Structure, and Their Reactions with Hydrosilanes
Liang Deng, Yafei Gao, Jian Sun
Three-coordinate NHC-cobalt(0)-olefin complexes in the forms of (NHC)Co(vtms)2 and (NHC)2Co(vtms) were prepared from the reactions of NHCs, CoCl2, vinylsilane, with alkali-metal reducing agents. These cobalt(0) complexes react with Ph2SiH2 to furnish diversified cobalt-silyl complexes.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01763

DOI: 10.1021/acs.inorgchem.7b01763

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