Crystal Growth & Design
Crystal Growth & Design
4 years ago

From Nd(III) and Pu(III) Oxalates to Oxides: Influence of Nitrilotris(methylenephosphonic acid) on Chemical Composition, Structure, and Morphology

From Nd(III) and Pu(III) Oxalates to Oxides: Influence of Nitrilotris(methylenephosphonic acid) on Chemical Composition, Structure, and Morphology
Stéphane Grandjean, Patrick Pochon, Pascal Roussel, Francis Abraham, Isabelle Bisel, Benedicte Arab-Chapelet, Anne-Lise Vitart, Murielle Rivenet, Blaise Haidon
The chemical composition, structure, and morphology of neodymium and plutonium oxalates have been modified by adding a complexing agent (NTMP) in the precipitation medium. The Nd/Pu complexation has been evidenced by UV−visible spectroscopy and leads to sphere-like agglomerate precipitation instead of rod-like particles.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00643

DOI: 10.1021/acs.cgd.7b00643

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