Inorganic Chemistry
Inorganic Chemistry
5 years ago

Generation of a Mn(IV)–Peroxo or Mn(III)–Oxo–Mn(III) Species upon Oxygenation of Mono- and Binuclear Thiolate-Ligated Mn(II) Complexes

Generation of a Mn(IV)–Peroxo or Mn(III)–Oxo–Mn(III) Species upon Oxygenation of Mono- and Binuclear Thiolate-Ligated Mn(II) Complexes
Ming-Hsi Chiang, Chien-Ming Lee, Wun-Yan Wu, Gene-Hsiang Lee, D. Scott Bohle
Mononuclear Mn(II) 2 mediates the two-electron reduction of O2 to generate a side-on Mn(IV)−peroxo 3 in which the metal-bound peroxo is further oxidized by 2 to form a mono-oxo-bridged dimeric Mn(III) 4.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01513

DOI: 10.1021/acs.inorgchem.7b01513

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