3 years ago

2-Thiabicyclo[3.3.1]nonanes Construction via Organocatalytic Asymmetric Formal [3+3] Cycloaddition

Jagjeet Gujral, Dhevalapally Ramachary, Srinivasa Reddy P.
Powerful asymmetric desymmetrization of thiane-3,5-diones through formal [3+3]-cycloaddition with alkyl vinyl ketones has been disclosed to access functionally rich 2-thiabicyclo[3.3.1]nonanes in very good yields with excellent enantio- and diastereoselectivities by using organocatalysis.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/ejoc.201701617

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