3 years ago

Front Cover: Structural and Computational Investigation of Intramolecular N···H Interactions in α- and β-Fluorinated 7-Azaindoline Amides (Eur. J. Org. Chem. /2018)

Front Cover: Structural and Computational Investigation of Intramolecular N···H Interactions in α- and β-Fluorinated 7-Azaindoline Amides (Eur. J. Org. Chem. /2018)
Masakatsu Shibasaki, Naoya Kumagai, Lennart Brewitz, Hidetoshi Noda
The Front Cover shows an intramolecular hydrogen-bonding interaction between the pyridyl nitrogen atom and a proton at the α-position of the carbonyl carbon atom of a fluorinated 7-azaindoline amide. The strength of the interaction can be tuned as a function of the electronic nature of the pyridyl nitrogen atom and the α-substituent, which was confirmed by X-ray crystallographic analysis, NMR analysis, and DFT calculations. More information can be found in the Full Paper by N. Kumagai, M. Shibasaki et al.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/ejoc.201800098

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