European Journal of Organic Chemistry
European Journal of Organic Chemistry
5 years ago

Nickel-Catalyzed Synthesis of Diaryl Sulfones from Aryl Halides and Sodium Sulfinates

Nickel-Catalyzed Synthesis of Diaryl Sulfones from Aryl Halides and Sodium Sulfinates
Shuai Liang, Marcella Drost, Saad Shaaban, Natalie Margraf, Nai-Wei Liu, Vanessa Luciano, Georg Manolikakes
A novel nickel-catalyzed cross-coupling of sulfinic acid salts with aryl halides is described. The reaction provides access to various diaryl sulfones in moderate to excellent yields. A broad range of functional groups and heteroaromatic compounds is tolerated under the reaction conditions.A nickel-catalyzed cross-coupling of sodium sulfinates with aryl halides is reported. The reaction provides diaryl sulfones in good yields and displays a broad tolerance towards functional groups.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/ejoc.201701478

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